Timetemperature diagram of intergranular corrosion in. Metals can contain multiple grains, and these are separated by a grain boundary. Intergranular corrosion degradation and surface engineering. The intergranular corrosion is called interdendritic corrosion or intercrystalline corrosion. Intergranular corrosion removalretreatment pilots of. The below tts diagram for a type 304 stainless steel shows as the time the steel has to. Intergranular stress corrosion cracking igscc is a type of corrosion due to applied forces on the granular boundaries of a material. The results highlight that intergranular corrosion is typically arrested. Furthermore, there are two main types of intergranular corrosion that are related to welding, for instance weld decay and knife line attack kla.
This causes depletion of chromium from the austenitic grains resulting in decreasing the corrosion protective passive film. Oct 23, 2014 thus, intergranular corrosion igc is a localized type of attack that occurs along microstructure grain boundaries and might also affects adjacent areas. In serious cases this can lead to the grains falling apart. Overvew of corrosion science, engineering and technology. Exfoliation corrosion is a further form of intergranular corrosion associated with high strength aluminum alloys.
In aqueous environments, metals may be exposed to not only uniform corrosion, but also to various types of local corrosion including pitting, crevice, intergranular, stress, and galvanic corrosion. This type of corrosion is a particular problem in stainless steels, however it can also occur in other metals. Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion. This condition is termed sensitization and it is shown schematically figure 2. Intergranular corrosion is a form of relatively rapid and localized corrosion associated with a defective microstructure known as carbide precipitation. Detection and quantification of intergranular corrosion. Studies on intergranular corrosion characteristics of cast duplex.
These tests do not provide a basis for predicting resistance to forms of corrosion other than intergranular, such as general corrosion, pitting, or stress corrosion cracking. Dvis aircraft corrosion experts are capable of evaluating corrosion failures involving steels, stainless steels, copper alloys and aluminum alloys. Intergranular corrosion article about intergranular. Intergranular corrosion is an attack on the grain boundaries of a metal. Before the igc test, all the samples were etched for 1 min with the solution of 50 ml hno 3 70% and 5 ml hf 48% in 945 ml of deionized water.
Galvanic diagram, intergranular diagram, crevice diagram, pitting diagram. Intergranular corrosion school of materials science and. Intergranular corrosion occurs because the electrochemical potential of the grain boundary is different from the grain core and, therefore, the grain boundary and grain core form, respectively, the anode and cathode of a tiny galvanic cell. A research program focused on understanding the intergranular corrosion igc and stress corrosion cracking scc behavior of aa6005a aluminum extrusions is presented in this dissertation.
Alloys that have been extruded or otherwise worked heavily, with a microstructure of elongated, flattened grains, are particularly prone to this damage. Steel is widely considered the most resilient and versatile materials in building and construction. Intergranular corrosion grain boundary attack and dropped grains. However, in this simulation the model does not capture the formation of lacy covers. Intergranular corrosion is caused by microsegregation of impurities and alloying elements on the grains boundaries. However, with modern steel making methods, it has become possible. New findings on intergranular corrosion mechanism of stabilized stainless steels. Intergranular corrosion is sometimes also called intercrystalline corrosion or interdendritic corrosion. There are a number of recognised tests when it comes to the intergranular corrosion testing of corrosion resistant alloys cra. Frankel fontana corrosion center, department of materials science and engineering, the ohio state university abstract the pitting and intergranular corrosion igc behavior of.
Intergranular corrosion facts and how to reduce the risk. Intergranular corrosion of tistabilized 11 wt% cr ferritic stainless steel for automotive exhaust systems article pdf available in corrosion science 5111. Some of the cold plate specimens were separated for destructive characterization of the extent of corrosion produced by the electrochemical process and to insure the induced corrosion was intergranular. Intergranular corrosion can occur in a variety of alloys, but is especially prevalent in the heat treatable 2xxx, 6xxx, and 7xxx systems. Stainless steels are usually delivered from the steel producer in the solutionannealed condition. To show that this corrosion was intergranular in nature and following the grain boundaries, the sample was etched using kellers reagent to. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Evaluating intergranular corrosion with metallography and xps chemical analysis. Effect of interrupted ageing treatment on the mechanical. The driving force of intergranular corrosion is the difference between the electrode potentials of the grain boundary and the grain itself, which form a galvanic cell in presence of an electrolyte. Postweld heat treatment to avoid stress corrosion cracking. In the presence of tensile strength, cracking may occur along grain boundaries and this type of corrosion is frequently called interranular stress corrosion cracking igscc or simply intergranular corrosion cracking.
Intergranular corrosion in austenitic stainless steel. Schematic diagram of the espi test system download scientific. After the igc test in accordance with isodis 11846 method b, heavy igc was observed at the surface of the extrusion. The chromium content of the carbide precipitates is very high, and since the diffusion rate of chromium in the austenite is low. Pdf intergranular and pitting corrosion susceptibilities. Schematic diagram of typical intergranular corrosion found in a. Intergranular corrosion can also be referred to as intergranular attack under a condition known as grain boundary depletion. The intergranular corrosion igc behavior of 6061 aluminum alloy extrusions was investigated. Intergranular corrosion was artificially induced in the face sheets of a series of cold plate specimens using an electrochemical process. Schematic of metal m anodic dissolution in pitting corrosion under a.
The igc behavior and mechanism of the crmnnincu austenitic. A thermodynamic calculation using the thermocalc program. Transitions between pitting and intergranular corrosion in. Intergranular corrosion and stress corrosion cracking of. An anode is a metal zone which loses electrons when exposed to an electrolyte, an electrolyte is a nonmetal electrical conductor, and a cathode is the zone where an oxidizing agent e. However, little igc occurred at the center plane of the extrusion thickness. Because intergranular corrosion occurs at the molecular level, microscopic examination is necessary to identify it. Measures to increase the resistance of stainless steels to intergranular corrosion caused by chromium carbide precipitation are solution annealing, lowering the carbon content and alloying with titanium or niobium stabilizing.
Corrosion types and prevention different types of corrosion. Metals and alloys, like other elements, have microstructures that can be described as grains. Figure gives the approximate time for austenitic stainless steels, grade a2 188 steels, with different carbon contents in the temperature zone between 550 c and 925 c before risk of intergranular corrosion occours. Dec 19, 2019 intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. Intergranular corrosion and residual stress determination of a duplex stainless steel pipeline girth weld b gideon1, l p ward2 1arv offshore, bangkok, thailand 2school of civil environmental and chemical engineering, rmit university. The intergranular corrosion test igc test was conducted by immersing in an aqueous chlorideperoxide solution which is based on astm g110. The relationship between igc and scc susceptibility and the mechanisms of scc in aa6005a extrusions were studied by examining two primary hypotheses. It is as a result of chromium depletion, mainly due to the precipitation of chromium carbides in the grain boundaries.
Pdf intergranular and pitting corrosion susceptibilities of. Pitting corrosion is a localized form of corrosion by which cavities or holes are produced in the material. Transitions between pitting and intergranular corrosion in aa2024. Intergranular corrosion what is intergranular corrosion.
When austenitic steels have been exposed for a period of time in the range of approximately 42. Pdf new findings on intergranular corrosion mechanism of. Intergranular corrosion results from chromium depletion in the alloy matrix near grainboundary chromium carbides and sometimes nitrides precipitated during welding or some other hightemperature exposure. This post will cover essential information about two forms of corrosion chosen by me, that are intergranular corrosion and stress corrosion. Each has similarities and differences both in the test solution, the test sample and the passfail criteria, and it is a good idea to familiarise yourself with these. A schematic of the finished product is shown in fig. Astm suggested citation style, chicago manual of style 17th edition. Frankel fontana corrosion center, department of materials science and engineering, the ohio state university abstract the pitting and intergranular corrosion igc behavior of various tempers of aa2024 was investigated in 1 m nacl.
Localised corrosion dealloying leaching dealloying is the removal of one element from the adealloying is the removal of one element from the alloy lloy the electrolyte. Since high temperature processing such as heat treatment is a common practice, many manufacturers wish to perform intergranular corrosion qualification testing on each batch, to ensure that the material has been processed correctly and does not show signs of corrosion susceptibility. Intergranular corrosion of low cr ferritic stainless steel 429. Corrosion products building up along the gb exert pressure betwe en the grains and the end result is a lifting or leafing effect. Intergranular corrosion igc is a selective attack in the vicinity of the grain boundaries of a stainless steel. Jun 05, 2017 dam2b session dec2016 material and hardware class. Yag continous wave laser was used as a thermal source together with an abb 6axes robot and a coaxial cladding unit made by rofin. Hsu center for nondestructive evaluation iowa state university ames, iowa 50011 introduction corrosion in all its forms is detrimental to the structural integrity of an aircraft and. Paper presented at stainless steel world 2005 conference, maastricht, the netherlands, 810 november 2005. The microstructure of metals and alloys is made up of grains, separated by grain boundaries. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. Apr 27, 2018 intergranular corrosion is a form of relatively rapid and localized corrosion associated with a defective microstructure known as carbide precipitation. Intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the. Dec 23, 2018 this is a corrosion type that attacks the boundaries of the metal crystallites, as opposed to attacking the surface of the metal.
Intergranular corrosion is localized attack along the grain boundaries, or immediately adjacent to grain boundaries, while the bulk of the grains remain largely unaffected. Corrosion of metallic surfaces is an electrochemical process typically involving an anode, electrolyte and a cathode. Intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. Intergranular stress corrosion cracking of welded steel twi. This type of corrosion was previously a potential risk for stainless steel because of its high carbon content. During heat treatment, these alloys are heated to a temperature that dissolves the alloying elements. The small amount of metal lost can result in significant loss of strength of the metal item. Effect of grain boundary characteristics on intergranular. In the presence of tensile stress, cracking may occur along grain boundaries and this type of corrosion is frequently called intergranular stress corrosion cracking.
Tracking the evolution of intergranular corrosion through twin. Postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels. Cleaning and corrosion control volume i corrosion program and corrosion theory 01 march 2005 this publication supersedes navair 011a509tm 1150034423, dated 1 may 2001 and navair 161540tm 1150034323to 11689, dated 1 sep 2000. However, to the knowledge of the authors, galvanic corrosion between different microphases is the most accepted theory for intergranular corrosion. To study intergranular corrosion igc characteristics, two cast grades of. Aviation, airplane, aircraft corrosion experts dvi aviation.
Drawing stresses are often relieved by thermal treatment. Intergranular corrosion an overview sciencedirect topics. Transitions between pitting and intergranular corrosion in aa2024 weilong zhang, g. The intergranular corrosion susceptibility of metastable austenitic. This form of corrosion is usually associated with chemical segregation effects impurities have a tendency to be enriched at grain boundaries or specific phases. Intergranular corrosion school of materials science.
Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. What is intergranular stress corrosion cracking igscc. A highly magni fied cross section of any commercial alloy shows the granular structure of the metal. Evaluating intergranular corrosion with metallography and. Pdf intergranular corrosion of tistabilized 11 wt% cr. Intergranular corrosion igc of nbti stabilized ferritic stainless steel fss 429 was investigated using. Jan 03, 20 corrosion of metallic surfaces is an electrochemical process typically involving an anode, electrolyte and a cathode. Pitting is considered to be more dangerous than uniform corrosion damage because it is more difficult to detect, predict and design against. Sensitization, intergranular attack, stress corrosion. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel.
A highly magni fied cross section of any commercial alloy shows the granular structure of. There is also a new method that consists in the application of software that. It was considered that igc was caused by the existence of precipitatefree zones pfzs because pfzs. The intergranular corrosion igc behavior of a new metastable austenitic. Sensitization involves the precipitation of chromium carbides at grain boundaries.
Intergranular and pitting corrosion susceptibilities of a supermartensitic stainless steel weldment. Intergranular corrosion attack along the grain boundaries of a material exfoliation corrosion extreme cases of intergranular corrosion stress corrosion metal is subjected to tensile stress in the presence of a corrosive environment fretting corrosion two surfaces. Intergranular corrosion intergranular corrosion is an attack on the grain boundaries of some alloys under specific renditions. The affected depths seem sufficient both to form preferential initiation sites oxidation at c and to assist intergranular propagation of defects andor cracks oxidation at 650c. For the achievement of the welding tests, a 3,3 kw nd. Intergranular attack is caused by the formation of chromium carbides fe,cr23c6 at grain boundaries, reducing the chromium content and the stability of the passive layer on stainless steels.
Intergranular corrosion removalretreatment pilots of america. Intergranular corrosion occurs when the grain boundaries in a metal form an anode and the interior of the grain acts as a cathode. Schematic diagram of typical intergranular corrosion found in a raaf ap3c aircraft. Stainless steel, corrosion and pitting corrosion researchgate, the. The igc and scc susceptibility of aa5182 was found to depend strongly on sensitisation heat treatments. This depletion occurs at certain timetemperature combinations which are sufficient to precipitate chromium carbide but insufficient to rediffuse chromium back into the austenite near the carbide. Low carbon content means less carbide precipitation in the heataffected zone during welding and a lower susceptibility to intergranular corrosion. Timetemperature diagram of intergranular corrosion in austenitic stainless steels. These tests do not provide a basis for predicting resistance to forms of corrosion other than intergranular, such as general corrosion, pitting, or stresscorrosion cracking. Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides.
Intergranular corrosion is a destruction of metal at grain boundaries. Intergranular corrosion and residual stress determination of a duplex stainless steel pipeline girth weld b gideon1, l p ward2 1arv offshore, bangkok, thailand 2school of civil environmental and chemical engineering, rmit university, australia summary welding of duplex stainless steel dss pipeline material for the oil and gas industry is now common. Many cases require highly specialized testing equipment, and dvis aviation corrosion experts have close relationships with universities and other commercial laboratories to provide a comprehensive set of testing solutions. Peridynamic modeling of intergranular corrosion damage. The etched samples were cleaned using deionized water and airdried. This situation can happen in otherwise corrosionresistant alloys, when the grain boundaries are depleted, known as grain boundary depletion, of the corrosion. Intergranular corrosion is a typical defect of austenitic and nickel alloys.
Intergranular corrosion is localized attack along the grain. In areas where corrosion is a concern, stainless steel products offer value and protection against these threats. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. The results highlight that intergranular corrosion is typically arrested inside.